There may be a cutscene triggered there (don't recall), that the game is having problems with. Try running the configuration program and switching to software mode temporarily, and maybe reduce the resolution, and see if you can get by the point it crashes.
Try deleting all of the files in the '
..\Divine Divinity\Run\Dynamic' folder.
This folder is used as a cache for the game. Files are created / copied there from the save game folder when you load, and written / copied from that folder when you save a game. The files will be re-created as required the next time you start Divinity. If there was a corrupt file in that folder, deleting the files should fix the problem.
Troubleshooting Tips (& manual install procedure) 
