I don't think the PC version has a screenshot function built in (I played the Xbox version), but you could hit the PrintScreen button, exit or Alt-Tab out of the game, and paste the image into a graphics program.

This topic is a fairly old, but there are Screenshot Programs you can use to automatically save screenshots. A couple others that I saved links for but haven't gotten around to trying yet are Gadwin PrintScreen and MWSnap, or check out some listed here.