If you only want to get one screenshot you should be able to hit the PrintScreen button, exit or Alt-Tab out of the game, and paste the image into a graphics program.
Alternately, there are programs to automatically save screenshots. I use PNGShot, but it hasn't been updated since 2003. A couple others that I saved links for but haven't gotten around to trying yet are Gadwin PrintScreen and MWSnap, or check out some listed here (I have not tried fraps, either).